Bismuth trichloride
Bismuth trichloride
CAS: 7787-60-2
Molecular Formula: BiCl3
Bismuth trichloride - Names and Identifiers
| Name | Bismuth trichloride |
| Synonyms | 232-123-2 Bismuth trichloride BisuMuth trichloride BisuMuth(Ⅲ) chloride Bismuth(Iii) Chloride bismuth(+3) trihydride cation trichloride Bismuth(III) chloride Vetec(TM) reagent grade |
| CAS | 7787-60-2 |
| EINECS | 232-123-2 |
| InChI | InChI=1/Bi.3ClH.3H/h;3*1H;;;/q+3;;;;;;/p-3/rBiH3.3ClH/h1H3;3*1H/q+3;;;/p-3 |
| InChIKey | JHXKRIRFYBPWGE-UHFFFAOYSA-K |
Bismuth trichloride - Physico-chemical Properties
| Molecular Formula | BiCl3 |
| Molar Mass | 315.34 |
| Density | 4.75 |
| Melting Point | 230-232°C(lit.) |
| Boling Point | 447°C(lit.) |
| Flash Point | 430°C |
| Water Solubility | decomposes |
| Solubility | Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol. |
| Appearance | White Powder |
| Specific Gravity | 4.75 |
| Color | White to beige or gray |
| Odor | Hydrochloric acid odor |
| Merck | 14,1262 |
| Storage Condition | no restrictions. |
| Stability | Stable, but reacts with water, moisture. |
| Sensitive | Hygroscopic |
| MDL | MFCD00003461 |
| Physical and Chemical Properties | White to light yellow crystals, easy deliquescence, hydrogen chloride odor, soluble in hydrochloric acid, nitric acid, in water decomposition of bismuth oxychloride. |
| Use | Used as analytical reagents and catalysts, but also for the preparation of bismuth salts |
Bismuth trichloride - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | R36/38 - Irritating to eyes and skin. R36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S37/39 - Wear suitable gloves and eye/face protection |
| UN IDs | 3260 |
| WGK Germany | 2 |
| RTECS | EB2690000 |
| TSCA | Yes |
| HS Code | 2827 39 85 |
| Hazard Class | 8 |
| Packing Group | III |
| Toxicity | LD50 orally in Rabbit: 3334 mg/kg |
Bismuth trichloride - Nature
Open Data Verified Data
white to light yellow crystals with a hydrochloric acid flavor. Melting Point: about 230~232 °c; Boiling Point: 447 °c; d54. 75. Deliquescence. Soluble in hydrochloric acid, nitric acid, ethanol, acetone, ethyl acetate and other organic solvents. In water or ethanol solution is decomposed into bismuth oxychloride precipitation.
Last Update：2024-01-02 23:10:35
Bismuth trichloride - Preparation Method
Open Data Verified Data
pure ammonia is introduced into the reaction equipment containing bismuth metal to remove air, and the equipment is dried at the same time. Then chlorine gas is introduced and the temperature is raised, and the bismuth chloride produced by the reaction is sublimated, the crude bismuth chloride can be obtained by cooling and condensation, and the crude product can be further purified by sublimation.
Last Update：2022-01-01 09:00:56
Bismuth trichloride - Introduction
It has the smell of hydrogen chloride and is soluble. When heated, it volatilizes and sublimates at about 430°C. Decomposes into bismuth oxychloride in water, which is soluble in hydrochloric acid, nitric acid, anhydrous ethanol, acetone and ethyl acetate.
Last Update：2022-10-16 17:28:49
Bismuth trichloride - Use
Open Data Verified Data
Analytical reagents. Catalysts. The manufacture of bismuth salts.
Last Update：2022-01-01 09:00:56
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